Chlorido(dimethyl sulfoxide)(pyridine-2-thiolato N-oxide-κ2 S,O)platinum(II)
نویسندگان
چکیده
The asymmetric unit of the title compound, [Pt(C(5)H(4)NOS)Cl(C(2)H(6)OS)], contains two independent complex mol-ecules having similar geometries. Each Pt(II) atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl sulfoxide mol-ecule and one terminal Cl(-) ion. The mol-ecules are linked into a three-dimensional framework by C-H⋯O and C-H⋯Cl hydrogen bonds.
منابع مشابه
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ2 N,O)platinum(II)
In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxyl-ate (pic) anionic ligand, one S atom of the dimethyl sulfoxide mol-ecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the ...
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